Journal article

Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes


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Publication Details

Author list: Foreman, M. R. S.; Hill, A. F., Ma, C. X.; Tshabang, N.; White, A. J. P.

Publication year: 2018

ISSN: 1477-9234

URL: https://pubs.rsc.org/en/content/articlelanding/2019/dt/c8dt04278k

Languages: English



A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S′,S′′-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S′,S′′-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].


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Last updated on 2022-29-11 at 11:35